Phase change,micro-structure and reaction mechanism during high temperature roasting of high grade rare earth concentrate
来源期刊：JOURNAL OF RARE EARTHS2020年第10期
论文作者：Huihui Wang Mei Li Dongliang Zhang Kai Gao Jianfei Li Zongxi Weng Wei Xu
文章页码：1140 - 1150
摘 要：The deposit of Bayan Obo in Inner Mongolia is the world’s largest rare earth element（abbreviated as REE）resource.The exploration of the theory of mineral formation of Bayan Obo is an important foundation for mineralogical research,and is the scientific basis for mining,industrial beneficiation,smelting and extraction,and processing and utilization.With the rapid development of science and technology,the demand for the utilization of rare earth elements is increasing,and the separation process between rare earth elements needs to be developed.The purpose of this paper is to provide high temperature experimental information for the formation and application of rare earth minerals.To this end,the mineral evolution of high-grade rare earth concentrates with increasing temperature and the migration of rare earths at different stages and their reaction mechanisms were studied.According to thermogravimetric analysis and differential scanning calorimetry（TG-DSC）,calcination was carried out at different temperature ranges,and the calcined products were characterized by X-ray diffraction（XRD）,Fourier transform infrared spectroscopy（FT-IR）,scanning electron micro scope and energy dispers ive spectrometer（SEM-EDS）and other analytical techniques.The re sults are shown in this process,the ra re earth phase is first converted into rare earth oxide and rare earth oxyfluoride.As the temperature increases,Ca5（PO4）3 F and a large number of self-shaped spherical Ca-RE-OF and Ca-RE-PO4 particles are formed,and the separation of La and Ce elements is discovered.Acco rding to the phase diagram analysis,the production of Ca5（PO4）3 F is due to the reaction of monazite and fluorite,and the phases CeF2 and Ce F3 are formed during the reaction.When it reaches 1500℃,barium ferrite is produced and a new substance containing Ba2+is formed.
Huihui Wang1,2，Mei Li1,2，Dongliang Zhang2，Kai Gao2，Jianfei Li2，Zongxi Weng2，Wei Xu2
1. Mining Research Institute,Inner Mongolia University of Science & Technology2. Key Laboratory of Green Extraction & Efficient Utilization of Light Rare-Earth Resources,Ministry of Education
摘 要：The deposit of Bayan Obo in Inner Mongolia is the world’s largest rare earth element（abbreviated as REE）resource.The exploration of the theory of mineral formation of Bayan Obo is an important foundation for mineralogical research,and is the scientific basis for mining,industrial beneficiation,smelting and extraction,and processing and utilization.With the rapid development of science and technology,the demand for the utilization of rare earth elements is increasing,and the separation process between rare earth elements needs to be developed.The purpose of this paper is to provide high temperature experimental information for the formation and application of rare earth minerals.To this end,the mineral evolution of high-grade rare earth concentrates with increasing temperature and the migration of rare earths at different stages and their reaction mechanisms were studied.According to thermogravimetric analysis and differential scanning calorimetry（TG-DSC）,calcination was carried out at different temperature ranges,and the calcined products were characterized by X-ray diffraction（XRD）,Fourier transform infrared spectroscopy（FT-IR）,scanning electron micro scope and energy dispers ive spectrometer（SEM-EDS）and other analytical techniques.The re sults are shown in this process,the ra re earth phase is first converted into rare earth oxide and rare earth oxyfluoride.As the temperature increases,Ca5（PO4）3 F and a large number of self-shaped spherical Ca-RE-OF and Ca-RE-PO4 particles are formed,and the separation of La and Ce elements is discovered.Acco rding to the phase diagram analysis,the production of Ca5（PO4）3 F is due to the reaction of monazite and fluorite,and the phases CeF2 and Ce F3 are formed during the reaction.When it reaches 1500℃,barium ferrite is produced and a new substance containing Ba2+is formed.
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