STUDY ON THE STRUCTURE OF IONIC CONDUCTOR FOR LiH-LiF-P2O5 GLASS SYSTEM
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition1990年第2期
论文作者：崔万秋 徐庆 丁彦
文章页码：23 - 28
摘 要：<正> The system of LiH-LiF-P2O5 ionic conductorglass is prepared in neutral atmosphere and glass-forming region is given. The structure and coor-dination of glass are analyzed by IR spectra. Ramanspectra and RDF（r）. The result indicates that the（PO4）, （PO3F） and （LiF4） tetrahedra are basicalstructure units of glass network and the coordina-tion number of Li is 4. The coordination number ofP is 4. The glass random network structure model isgiven. The study on structure shows that Li+, H- andpartial F- are charge carriers in glass system.
崔万秋，徐庆，丁彦
摘 要：<正> The system of LiH-LiF-P2O5 ionic conductorglass is prepared in neutral atmosphere and glass-forming region is given. The structure and coor-dination of glass are analyzed by IR spectra. Ramanspectra and RDF（r）. The result indicates that the（PO4）, （PO3F） and （LiF4） tetrahedra are basicalstructure units of glass network and the coordina-tion number of Li is 4. The coordination number ofP is 4. The glass random network structure model isgiven. The study on structure shows that Li+, H- andpartial F- are charge carriers in glass system.
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