Synthesis, structure and photoluminescent properties of a new Eu（Ⅲ） complex with 5-bromoisophthalic acid
来源期刊：JOURNAL OF RARE EARTHS2011年第6期
论文作者：刘光祥 李杏龙 任小明
文章页码：511 - 515
摘 要：The self-assembly of 5-bromoisophthalic acid （H2BIPA） with Eu（NO3）3·6H2O under the hydrothermal conditions gave a 3D coordination polymer, Eu2（BIPA）3（CH3CH2OH） （1）, which was characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 displayed an unusual three-dimensional network of a rare （4,6）-connected （48.66.8）2（44.62）2（42.84） topology, which was different from Eu2（BDC）3（H2O）2 （BDC=isophthalate）, because the -Br substituent of the isophthalate resulted in the different electronic effects and the steric hindrance to change the coordination modes of carboxylate groups in the assembled process. Moreover, the luminescent properties of 1 were also investigated in the solid state.
刘光祥1,2，李杏龙1，任小明1
1. Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University2. State Key Laboratory of Coordination Chemistry, Nanjing University
摘 要：The self-assembly of 5-bromoisophthalic acid （H2BIPA） with Eu（NO3）3·6H2O under the hydrothermal conditions gave a 3D coordination polymer, Eu2（BIPA）3（CH3CH2OH） （1）, which was characterized by elemental analysis, IR and single-crystal X-ray diffraction. Complex 1 displayed an unusual three-dimensional network of a rare （4,6）-connected （48.66.8）2（44.62）2（42.84） topology, which was different from Eu2（BDC）3（H2O）2 （BDC=isophthalate）, because the -Br substituent of the isophthalate resulted in the different electronic effects and the steric hindrance to change the coordination modes of carboxylate groups in the assembled process. Moreover, the luminescent properties of 1 were also investigated in the solid state.
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