Trans. Nonferrous Met. Soc. China 28(2018) 376-384
Direct electrolytic preparation of chromium metal in CaCl2-NaCl eutectic salt
Zheng-wei LIU1,2,3, Hong-ling ZHANG1,2, Li-li PEI1,2, Yi-lang SHI4, Zai-hua CAI4, Hong-bin XU1,2, Yi ZHANG1,2
1. CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
3. University of Chinese Academy of Sciences, Beijing 100049, China;
4. Hubei Zhenhua Chemical Co., Ltd., Huangshi 435001, China
Received 16 November 2016; accepted 20 April 2017
Abstract:
The electro-reduction of chromium oxide (Cr2O3) was investigated in an equimolar mixture of CaCl2-NaCl molten salt at 800 °C for developing a more efficient process for chromium preparation. Cyclic voltammetry and potentiostatic electrolysis were used to study the electro-reduction of the Cr2O3-loaded metallic cavity electrode. In addition, a number of parameters affecting the rate and extent of Cr2O3 electrolysis were considered to better understand the electrolysis process. The results demonstrate that CaCl2-NaCl molten salt is applicable for preparing Cr directly from Cr2O3 and the electrolysis parameters exert great influence on the cathode product. Under optimal experimental conditions, nodular Cr with an oxygen content of 0.5% (mass fraction) was obtained without any chromium carbides detected by XRD. Furthermore, the relatively high solubility of CaO and quite rapid crystal growth result in the formation of large platelet CaCr2O4, and the addition of NaCl to CaCl2 results in several variations on the electrolysis process and the product morphology from pure CaCl2 molten salt.
Key words:
electrolysis; chromium; chromium oxide; CaCl2-NaCl molten salt;
1 Introduction
Chromium (Cr) metal is an attractive engineering material for many areas of applications owing to its properties of high melting point and considerable corrosion resistance [1,2]. Cr metal is predominantly produced by aluminothermic reduction of Cr2O3 at high temperature above the melting point of Cr. The other process is to use CrO3 aqueous electrolyte electrolysis. However, the side reactions, chiefly the redox cycling of the multi-valence chromium ions (mainly Cr2+, Cr3+ and Cr6+) and Cr3+/Cr electrode potential being more negative than that of H+/H2, account for the low current efficiency and the hydrogen brittleness [3]. In addition, there are laboratory studies about Cr electro-deposition from expensive CrCl2, CrCl3 or K3CrF6 in molten salt [3-5].
The FFC-Cambridge process, based on the concept of cathodic oxygen ionization of solid oxide in CaCl2-based molten salt, has been demonstrated for the successful preparation of metals and alloys, such as titanium [6-9], niobium [10,11], tantalum [12,13], silicon [14], germanium [15], zirconium [16,17], CeCo5 [18], and ZrMn5 [19]. Particularly, researchers have validated the feasibility of the electro-reduction of Cr2O3, and a series of experiments have been performed to determine the influence of the electrolysis time, electrolysis voltage and anode areas on the electrolysis process in CaCl2 molten salt [1,2,20]. However, pure CaCl2 has a high melting point of 782 °C, hence, resulting in the electrolysis temperature as high as 900-950 °C. Moreover, chromium carbide was detected after Cr2O3 electrolysis due to the high temperature and high solubility of O2- in CaCl2 molten salt [20,21]. A process is always desired if it can proceed without external heating or at a lower temperature, if heating is inevitable, because of its relative energy-saving, mild reaction conditions and reduced corrosion property [10]. Substitutional CaCl2-based electrolyte with low melting temperature has been selected to perform the FFC process. For instance, it is demonstrated experimentally that CaCl2-NaCl eutectic salt as the electrolyte is available and could be applied to preparing Nb [10], Ta [12], Ge [15], and U [22]. The addition of NaCl or other alkali or alkaline earth chloride to CaCl2 may affect the electrolysis of solid oxide in several manners: both desired and undesired [2]. GORDO et al [2] reported that CaCl2-NaCl molten salt is expected to have a lower capability to accommodate O2-, leading to a lower background current and alleviative graphite corrosion.
Herein, the equimolar mixture of CaCl2 and NaCl was selected as the molten salt. CVs and potentiostatic electrolysis of Cr2O3 in CaCl2-NaCl molten salt were investigated. Experimental work was also undertaken to study the influence of process variables on the extent and rate of electro-reduction of Cr2O3. Particular attention was paid to the role of Ca2+ and Na+ involved in the formation of intermediate product, because intermediate CaxMyOz (M means metal) was often detected, whereas NaxMyOz was rarely found during the electrolysis of metal oxides in CaCl2-NaCl molten salt [10,12,15,22]. Finally, the influence of CaCl2-NaCl and pure CaCl2 on the electrolysis process and the product morphology was compared.
2 Experimental
Cr2O3 (>99%, mass fraction) powders of 1.5 g were compressed into compact cylinder pellet with a uniaxial pressure of 170 MPa in a 13 mm diameter steel die. These pellets were subsequently sintered at a specific temperature for 3 h. The porosity of the as-sintered pellet was measured by the Archimedes method. The sintered pellets were then drilled, connected into a current collector and assembled as an oxide cathode. Anhydrous CaCl2 (>96%, mass fraction) and NaCl (>99.5%, mass fraction) were blended with mole ratio of 1:1 in alumina crucible (99%, mass fraction). The details of the preparation for the electrolyte were described in Ref. [10].
CV curves of Cr2O3 in CaCl2-NaCl molten salt were recorded using the metallic cavity electrode (MCE) according to Ref. [23], with a computer-assisted solartron electrochemical workstation employed. Cr2O3 powders were manually pressed into the cavity of the MCE, which functioned as working electrode during CV test. A graphite rod and Ag/Ag+ electrode (10% AgCl, 45% NaCl and 45% KCl in mole fraction, sealed in alumina pipe) were used as the counter and reference electrodes, respectively [24]. The CV tests were conducted with a scan rate of 100 mV/s, with the potential ranging from 0 to -1.8 V (vs Ag/Ag+). Potentiostatic electrolysis was performed at -1.4 V (vs Ag/Ag+) using MCE loaded with Cr2O3. After potentiostatic experiment for 300 s, the Mo/Cr2O3 sample was retrieved, washed with dilute HCl solutions and dried.
The electrolysis of solid Cr2O3 was performed in a sealed stainless steel reactor, in which the center was located in the alumina crucible holding the molten salt. A high-density graphite rod of 15 mm in diameter was used as the anode. Both the anode and cathode current collectors were enclosed by an alumina pipe for insulation. The cell was flushed with argon while it was heated to the required temperatures and kept leak-proof to maintain an inert atmosphere of high purity argon gas. On reaching electrolysis temperature of 800 °C, the pre-electrolysis of the thermally dried molten salt was conducted using a constant voltage of 2.0 V applied between the graphite anode and stainless steel cathode to remove the residue moisture and metallic impurities from the electrolyte. After pre-electrolysis, Cr2O3 electrode was inserted into the molten salt and a constant voltage varying from 2.5 to 3.2 V was imposed between the anode and oxide cathode with approximately 30 mm apart from each other. The graphite anode was immersed to a salt depth of 3 cm corresponding to a geometric surface area of 16 cm2. After a predetermined time, the electrolysis was terminated and the cathode was quickly lifted above the molten salt, cooled in argon atmosphere to room temperature and removed from the reactor. These recovered pellets were subsequently washed with distilled water to remove the solidified salt. They were further rinsed with dilute HCl solutions with pH 3. Such vigorous procedure could confirm that all the salts attached on the pores of the pellets could be eliminated from the electrolysis product. Finally, the sample was dried in a freezer dryer.
The microstructural composition of the sintered or electrolyzed pellet was observed using a scanning electron microscope (SEM) coupled with an energy- dispersive X-ray analysis (EDXA) attachment. Various phase compositions present in the prepared samples were determined by X-ray diffraction (XRD) with the scan range set from 10° to 90° after grinding the pellet. The oxygen content was determined by pulsed infrared melting-infrared thermal conductivity detection analysis (PIM-ITC).
3 Results and discussion
3.1 Electrochemical test
CaCl2-NaCl eutectic salt with mole ratio of 1:1 has a low melting point of 504 °C, whereas most-frequently used CaCl2 has a high melting point of 782 °C, thus giving the eutectic salt potential to be employed at a lower working temperature. Table 1 illustrates the theoretical electrode potentials of Cr2O3, CaCl2 and NaCl at 800 °C. As can be evidently observed, the theoretical decomposition potential of Cr2O3 is far less than that of individual pure salt CaCl2 and NaCl. Attention should be especially paid to the calcium chromite (CaCr2O4), which is believed to be an intermediate product during the electrolysis of Cr2O3 [1,2,25]. The theoretical decomposition potential is higher than that of Cr2O3, but still lower than that of individual salt. Thus, thermodynamically applicable CaCl2-NaCl eutectic salt could be employed as the molten salt electrolyte when voltage of 2.5-3.2 V in this context is applied between the oxide cathode and graphite anode. Besides, CaCl2–NaCl eutectic salt has a higher electrical conductivity and lower viscosity compared to CaCl2 molten salt, providing a better flow field environment for the electrolysis.
Table 1 Electrochemical properties of selected chromium compounds and chlorides at 800 °C with reference to Ca2+/Ca couple
The electrochemical behavior of Cr2O3 in CaCl2-NaCl molten salt at 800 °C was investigated by CV measurement and potentiostatic electrolysis. Figure 1 presents the CV curves of blank MCE (solid line) and MCE loaded with Cr2O3 (dash line) in CaCl2-NaCl molten salt. Peak C1 is the only peak observed in the CV curves of blank MCE and hence could be attributed to the cathodic formation of Ca and/or Na in CaCl2-NaCl molten salt. However, after loading Cr2O3 into MCE, one additional reduction peak at -1.4 V (peak C 2) is detected during the negative scan. As a result, peak C 2 is ascribed to the electro-reduction of solid Cr2O3 since peak C 2 is the only cathodic peak detected after loading Cr2O3 into MCE. Theoretically, the electro-reduction potential of Cr2O3 is about 1.235 V higher vs Ca2+/Ca (or 1.18 V vs Na+/Na). The narrow gap between the Cr2O3 and Ca2+/Ca reduction potential (Fig. 1) elucidates a high overvoltage necessitated to advance the Cr2O3 electro-reduction. Actually, similar high overvoltage was observed during the CV test of Cr2O3 in CaCl2 molten salt at 900 °C [23]. Potentiostatic electrolysis of Cr2O3 was then performed at -1.4 V (vs Ag/Ag+). The SEM image of the product from the potentiostatic electrolysis of MCE loaded with Cr2O3 powders in CaCl2-NaCl molten salt at 800 °C for 300 s displays nodular particles of 200 nm in Fig. 2. The EDXA result confirms that the nodular particles are Cr metal with residue oxygen.
Fig. 1 CV curves of blank MCE and MCE loaded with Cr2O3 in CaCl2-NaCl molten salt at 800 °C and scan rate of 100 mV/s
Fig. 2 SEM image of product from potentiostatic electrolysis (-1.4 V (vs Ag/Ag+)) of MCE loaded with Cr2O3 in CaCl2- NaCl molten salt at 800 °C for 300 s
3.2 Influence of sintering temperature
Figure 3 shows the SEM images of the fracture surface of Cr2O3 pellet sintered at different temperatures, from which the temperature dependence of the microstructures is clearly observed, especially at high sintering temperatures. The particles of the pellet exhibit an increase in size as the sintering temperature is raised from 1100 to 1400 °C [2]. As reported, the O2- generated at the oxide cathode first proceeded across the particle in the solid form, followed by its diffusion through the pores of the cathode and finally reached the anode where O2- was oxidized to CO/CO2 [26]. Thus, it would be reasonably speculated that O2- would take a longer distance to diffuse to the particle’s outer surface from the inside for the pellet with larger size distribution or sintered at higher temperature. Although the pellets sintered at different temperatures have a similar porosity of about 35%, the boundary between Cr2O3 particles is more closely connected to each other at higher sintering temperatures. Therefore, there would be a compromise for O2- diffusion rate due to the enlarged diffusion distance and the dense structure as a result of increased sintering temperature. Figure 4 shows the XRD patterns of cathode pellets subjected to electrolysis at an applied voltage of 3.0 V for 8 h, which demonstrates that the cathode pellet, sintered at lower temperature or with smaller size distribution, could be totally electrolyzed to Cr metal. In contrast, the cathode pellet sintered at higher temperature could only be partially electrolyzed as intermediate product CaCr2O4 still remains. Accordingly, Figs. 5(a) and (b) show SEM images of the electrolysis products at sintering temperatures of 1100 and 1400 °C, respectively. The particles in Fig. 5(a) show uniformly nodular morphology of around 500 nm, which are confirmed to be Cr metal by EDXA result. The particles in Fig. 5(b) display two obviously dissimilar micro- structures, being nodular and irregular morphologies. In combination of the XRD result (Fig. 4), the irregular morphology is believed to be CaCr2O4 [1,2]. As a result, increasing the sintering temperature slows down the overall electrolysis rate to some extent and leads to partial oxygen removal from the cathode under the present experimental condition. The complete electrolysis of the oxide cathode, namely the highest electrolysis rate of Cr2O3 pellet observed in Fig. 5(a), is hence attributed to the smaller particle size of Cr2O3 pellet sintered at low temperature of 1100 °C, which means that mass transfer of O2- across the particle in the solid form is the rate-controlling step. Therefore, small particles are preferably employed in order to fulfill a complete electrolysis, while larger particles should be tried best to avoid, on account of not only decreasing the sintering temperature but also accelerating the rate of the electrolysis.
Fig. 3 SEM images of cross sections of Cr2O3 pellets sintered at different temperatures
Fig. 4 XRD patterns of electrolysis product at 3.0 V for 8 h and sintered at different temperatures
3.3 Influence of electrolysis voltage
Fig. 5 SEM images of electrolysis product at 3.0 V for 8 h and sintered at different temperatures
Fig. 6 Current-time plots at different voltages between cathode and anode
The electro-reduction of Cr2O3 pellet under varying voltages from 2.5 to 3.2 V for 8 h was conducted. The pellets used were prepared by die-pressing and sintered at 1100 °C for 3 h. The typical current-time behaviors at different voltages are presented in Fig. 6. The currents recorded at 2.8, 3.0 and 3.2 V show similar features. Initially, it quickly reaches current peak and then gradually decays to the background current. The exception is the electrolysis of Cr2O3 pellet at 2.5 V, the lowest applied voltage in this work. The recorded current quickly reaches initial current peak, but the current plateau endures for a longer time. The current at later stage is higher than that at higher voltage. According to the metal/oxide/electrolyte interface (3PI) theory [1], it may be the slow 3PI propagation toward the inside of pellet that causes long-time current plateau at low applied voltage of 2.5 V. Besides, the oxygen content of the electrolysis product measured by PIM-ITC method is determined to be high about 9% (mass fraction), demonstrating an incomplete electrolysis. The incomplete electrolysis of Cr2O3 might lead to the high current at later stage. Figure 7 shows the XRD patterns of the products after electrolysis at different voltages, indicating that voltage of 2.5 V is high enough to electrolyze Cr2O3 to Cr metal. However, the residual oxygen content is high (about 9%) as described in Fig. 8. When the electrolysis voltage increases to 3.2 V, Cr2O3 is fully electrolyzed to Cr metal with oxygen content as low as 0.5% (mass fraction). In practice, the voltage applied between the cathode and anode is not entirely consumed between the graphite anode and Cr2O3 cathode, if concentration polarization and voltage loss due to circuit resistance is taken into account. These results clarify that high voltage is crucial in order to accomplish a complete electrolysis of Cr2O3 with low oxygen content, while low voltage could only realize partial oxygen removal. The SEM image of the product after electrolysis at 2.5 V in Fig. 9(a) exhibits that some platelet morphologies are surrounded by nodular particles, of which the platelet morphologies are assigned to CaCr2O4 and nodular particles of Cr metal [1,2,26], showing the incomplete electrolysis. In contrast, the SEM image of the product after electrolysis at 3.2 V in Fig. 9(b) displays nodular Cr particle morphology.
Fig. 7 XRD patterns of electrolysis product at different voltages between cathode and anode for 8 h
Fig. 8 Residual oxygen content detected by PIM-ITC method at different voltages between cathode and anode
Fig. 9 SEM images of electrolysis product at different voltages between cathode and anode for 8 h
3.4 Influence of electrolysis duration
Figure 10 shows the XRD patterns obtained from specimens whose electrolysis was terminated after different periods of time from 0.25 to 8 h at 3.0 V. Sample obtained after electrolysis for 0.25 h is found to consist predominantly of Cr2O3. At the same time, metal Cr peak begins to show up, although Cr peak is quite minor. This could be attributed to little amount of Cr metal initially formed on 3PI interface. With the electrolysis process progressing, samples recovered for 0.5 and 1 h are primarily composed of Cr2O3, Cr and CaCr2O4. And samples retrieved at reaction time longer than 2 h contain mainly Cr metal, although there is small amount of CaCr2O4. Finally, the whole pellet turns to Cr metal after electrolysis for 8 h. In summary, with the electrolysis process progressing, the amount of Cr2O3 gradually decreases and the amount of Cr rises, while CaCr2O4 only exists temporarily as an intermediate.
CaCr2O4 with a diameter of micrometers is described above during the electrolysis of Cr2O3 in CaCl2-NaCl molten salt. However, no intermediate product such as NaCrO2 is detected. Likewise, similar phenomenon has been covered in the case of the electrolysis of other metal oxides, such as Ta2O5, Nb2O5, GeO2 in CaCl2-NaCl molten salt. For instance, during the electrolysis process of Nb2O5 to Nb in CaCl2-NaCl molten salt, Nb2O5 cathode undergoes several intermediate phases, such as CaNb2O6, CaNbO3, Ca2Nb2O7, and finally changes to Nb metal, whereas no NaxNbyOz compounds are detected [12,27]. In order to investigate the reason why no NaCrO2 compound is generated in CaCl2-NaCl molten salt, experiment was conducted in pure NaCl molten salt at 900 °C with a applied voltage of 3.0 V between the anode and cathode. Only the very thin surface of the pellet turns to grey after electrolysis for 8 h, whereas the inside remains unchanged and resembles the starting precursor Cr2O3. This confirms that some mild reactions occur in pure NaCl molten salt, but only slightly. A typical SEM investigation obtained from the grey layer of partially electrolyzed pellet is presented in Fig. 11. Different morphologies of large platelets and small particles are observed. The EDXA results in Table 2 show that the large platelets are mainly composed of Cr, Ca, and O with small amount of Na detected. The presence of Ca detected by EDXA in the as-obtained product in pure NaCl molten salt is due to the impurity of analytical purity NaCl. Similarly, QIU el al [23] reported that the Mg observed by EDXA in the as-obtained product in pure CaCl2 molten salt is due to the impurity of analytical purity CaCl2. Small particles are mainly composed of Cr and O, indicative of partial electrolysis of Cr2O3. So, it could be concluded that Ca plays a crucial role in the electrolysis process, while sodium exerts little influence on the process even in pure NaCl molten salt.
Fig. 10 XRD patterns of electrolysis product at 3.0 V for different time
LIU et al [28] proposed the reaction pathway of the electro-reduction of Cr2O3 to explain the mechanism for the generation of CaCr2O4.
Fig. 11 Typical SEM image of electrolysis product in NaCl molten salt
Table 2 EDXA results of electrolyzed products in NaCl molten salt in Fig. 11
By analogy, the same mechanism proposed above could be applied to explaining the fact that the NaCrO2 forms in CaCl2–NaCl molten salt. As seen from Eqs. (2) and (3), the chemical reaction of NaCrO2 is much favorable than that of CaCr2O4 from their respective oxides thermodynamically. However, the fact that no any NaCrO2 is found in the product runs counter to the thermodynamic prediction. There might be several reasons that lead to the phenomenon. The first is due to the low solubility of Na2O dissolved in CaCl2–NaCl molten salt, which is disadvantageous for the formation of NaCrO2 according to Eq. (3). In comparison, CaCl2 could accommodate a reasonably large quantity of CaO (about 20%, mole fraction), which allows O2- to dissolve in the molten salt [29]. Thus, the high solubility of CaO dissolved in the molten salt is favorable for the formation of CaCr2O4. The second could be attributed to CaCr2O4 quick growth. In previous researches, ALEXANDER et al [7] reported that in the reaction of TiO with CaTiO3 to form CaTi2O4, rapid growth is the main reason behind the large size of CaTi2O4 particles. In this context, CaCr2O4 shows a typical morphology of large platelet of micrometers. Therefore, it would be reasonably assumed that CaCr2O4 grows with a quite rapid crystal growth.
Cr2O3(s)+6e→2Cr(s)+3O2- (at 3PI) (1a)
O2-+Ca2++Cr2O3(s)=CaCr2O4(s)(at oxide-electrolyte interface) (1b)
Cr2O3+CaO=CaCr2O4,
△G=-73.6 kJ/mol (at 800 °C) (2)
Cr2O3+Na2O=2NaCrO2,
△G=-81.02 kJ/mol (at 800 °C) (3)
3.5 Comparison of molten salt medium
As discussed above, the addition of NaCl to CaCl2 salt alters the molten salt nature and affects the electrolysis of solid Cr2O3 in a number of ways, desired and undesired. Several different features are easily observed from CaCl2 molten salt when CaCl2-NaCl molten salt is adopted as the electrolyte. Firstly, the background current at later stage of the electrolysis is much smaller than that in CaCl2 molten salt as predicted due to lower solubility of O2- [20], thus a higher current efficiency becomes possible. Secondly, the final Cr particles possess the nodular morphology and have a size distribution ranging from 400 to 600 nm as displayed in Figs. 5(a) and 9(b). However, both nodular and cubic Cr particles were found during the electrolysis of Cr2O3 in CaCl2 molten salt [1,2]. GORDO et al [2] reported that cubic Cr particles could be obtained if the electrolysis voltage is lower than 2.8 V. CHEN and FRAY [30] explained that the cubic Cr particles resulted from the preferential growth which could in principle convert the initial spherical nuclei or small crystallites into larger particles of cubic shapes. In CaCl2-NaCl molten salt, cubic Cr particles are never detected. Though the reason is not clear, it must be related to the eutectic salt providing a specific environment for the electrolysis of Cr2O3. The nodular Cr morphology is similar to that obtained in CaCl2 molten salt, except that the size is quite smaller than that 1-3 μm obtained in CaCl2 molten salt, as shown in Fig. 12 [1,2,28]. This is attributed to the lower molten salt temperature of 800 °C applied under the experimental conditions as high temperature would result in sintering of Cr particles, which would allow the particles to grow into 1 μm or larger in diameter in CaCl2 molten salt at 900 °C. Cr2O3 is fully electrolyzed to Cr metal with oxygen content as low as 0.5% (mass fraction) at 3.2 V. In comparison with the oxygen content 0.2% (mass fraction) produced in CaCl2 molten salt, the oxygen content is a little higher [2,20,28]. Figure 13 shows a typical TEM image of the surface of Cr particles after electrolysis in CaCl2-NaCl molten salt. Clearly, a thin coating (≈5 nm in thickness) is revealed and should be attributed to partial oxidation of the Cr surface. WU et al [11] reported similar oxide layer during the electro- reduction of Nb2O5 to Nb metal. The coating is comparable in uniformity and might have formed during post-electrolysis processing operation including washing in water and exposure to air [11]. Assuming Cr particles to be spherical of 1 μm in diameter and the oxide layer to be uniform with a similar thickness after electrolysis in CaCl2 molten salt, the oxygen content of Cr metal produced in CaCl2-NaCl molten salt can be calculated to be twice higher than that produced in CaCl2 molten salt due to the small particle size distribution of 500 nm. This confirms a significant contribution of the oxide coating to the overall oxygen content in the electrolysis product. Thirdly, all peaks of the product after electrolysis could be assigned to Cr metal in Fig. 10(f). And no any chromium carbide is detected, denoting that CaCl2-NaCl molten salt with a lower working temperature could effectively avoid the carbon contamination. Herein, the lower temperature used not only reduces the corrosion of the graphite anode, but also decreases the chance of the chemical combination of Cr and C to form the chromium carbides.
Fig. 12 SEM image of nodular Cr product at 3.0 V for 8 h in CaCl2 molten salt at 900 °C
Fig. 13 TEM image of electrolysis product at 3.2 V for 8 h between cathode and anode
4 Conclusions
1) CVs and potentiostatic electrolysis of MCE loaded with Cr2O3 were studied to confirm the electro- reduction mechanism of rod-like Cr2O3 to Cr at a potential of -1.40 V (vs Ag/Ag+).
2) Metal Cr was successfully prepared from the electro-reduction of Cr2O3 in the equimolar CaCl2+NaCl. The results indicated that Cr without chromium carbides detected could be achieved under the optimized conditions: pellet sintering temperature 1100 °C, voltage 3.2 V, duration 8 h. The as-obtained nodular Cr with oxygen content of 0.5% (mass fraction) has a diameter range from 400 to 600 nm.
3) It is assumed that the relatively high solubility of CaO and quite rapid crystal growth result in the formation of large platelet CaCr2O4. In comparison, no any NaCrO2 compounds are generated due to the low solubility of Na2O in CaCl2-NaCl molten salt, although NaCrO2 is much more favorable to form thermodynamically.
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在CaCl2-NaCl共融盐中直接电解制备金属铬
刘政伟1,2,3，张红玲1,2，裴丽丽1,2，石义朗4，蔡再华4，徐红彬1,2，张 懿1,2
1. 中国科学院 绿色过程与工程重点实验室(中国科学院过程研究所)，北京 100190；
2. 中国科学院过程工程研究所 湿法冶金清洁生产技术国家工程实验室，北京100190；
3. 中国科学院大学，北京 100049；
4. 湖北振华化学股份有限公司，黄石 435001
摘 要：通过考察800 °C下固体三氧化二铬(Cr2O3)在等摩尔CaCl2-NaCl熔盐中的电还原过程，得到一个更高效的金属铬制备工艺。利用循环伏安和恒电势电解法考察负载Cr2O3的金属空洞电极的电还原过程，并考察影响Cr2O3电解速率和电解程度的重要电解参数。结果表明：CaCl2-NaCl熔盐可用作直接电解Cr2O3制备金属铬的熔盐；电解参数对电解产品质量影响明显。在最佳电解条件下，得到氧含量为0.5% (质量分数)的节支状金属铬产品，且X射线衍射法没有检测到任何碳化铬存在。此外，CaO较高的溶解度和CaCr2O4较快的晶体生长速率导致大颗粒片状CaCr2O4的生成。与纯CaCl4相比，在CaCl2中添加NaCl可明显改变电解过程和产物形貌。
关键词：电解；金属铬；氧化铬；CaCl2-NaCl熔盐
(Edited by Wei-ping CHEN)
Foundation item: Project (2013CB632600) supported by the National Basic Research Program of China; Projects (21376251, 21406233) supported by the National Natural Science Foundation of China; Project supported by the Fund of Hubei Zhenhua Chemical Co., Ltd., China
Corresponding author: Hong-ling ZHANG; E-mail: hlzhang@ipe.ac.cn
DOI: 10.1016/S1003-6326(18)64671-0
Abstract: The electro-reduction of chromium oxide (Cr2O3) was investigated in an equimolar mixture of CaCl2-NaCl molten salt at 800 °C for developing a more efficient process for chromium preparation. Cyclic voltammetry and potentiostatic electrolysis were used to study the electro-reduction of the Cr2O3-loaded metallic cavity electrode. In addition, a number of parameters affecting the rate and extent of Cr2O3 electrolysis were considered to better understand the electrolysis process. The results demonstrate that CaCl2-NaCl molten salt is applicable for preparing Cr directly from Cr2O3 and the electrolysis parameters exert great influence on the cathode product. Under optimal experimental conditions, nodular Cr with an oxygen content of 0.5% (mass fraction) was obtained without any chromium carbides detected by XRD. Furthermore, the relatively high solubility of CaO and quite rapid crystal growth result in the formation of large platelet CaCr2O4, and the addition of NaCl to CaCl2 results in several variations on the electrolysis process and the product morphology from pure CaCl2 molten salt.
