Optimization of low-temperature alkaline smelting process of crushed metal enrichment originated from waste printed circuit boards
来源期刊：中南大学学报(英文版)2015年第5期
论文作者：GUO Xue-yi LIU Jing-xin
文章页码：1643 - 1650
Key words：low-temperature alkaline smelting; waste printed circuit board; amphoteric metals; central composite design; conversion
Abstract: A novel low-temperature alkaline smelting process is proposed to convert and separate amphoteric metals in crushed metal enrichment originated from waste printed circuit boards. The central composite design was used to optimize the operating parameters, in which mass ratio of NaOH-to-CME, smelting temperature and smelting time were chosen as the variables, and the conversions of amphoteric metals tin, lead, aluminum and zinc were response parameters. Second-order polynomial models of high significance and 3D response surface plots were constructed to show the relationship between the responses and the variables. Optimum area of 80%-85% Pb conversion and over 95% Sn conversion was obtained by the overlaid contours at mass ratio of NaOH-to-CME of 4.5-5.0, smelting temperature of 653-723 K, smelting time of 90-120 min. The models were validated experimentally in the optimum area, and the results demonstrate that these models are reliable and accurate in predicting the smelting process.
GUO Xue-yi(郭学益), LIU Jing-xin(刘静欣)
(School of Metallurgy and Environment, Central South University, Changsha 410083, China)
Abstract:A novel low-temperature alkaline smelting process is proposed to convert and separate amphoteric metals in crushed metal enrichment originated from waste printed circuit boards. The central composite design was used to optimize the operating parameters, in which mass ratio of NaOH-to-CME, smelting temperature and smelting time were chosen as the variables, and the conversions of amphoteric metals tin, lead, aluminum and zinc were response parameters. Second-order polynomial models of high significance and 3D response surface plots were constructed to show the relationship between the responses and the variables. Optimum area of 80%-85% Pb conversion and over 95% Sn conversion was obtained by the overlaid contours at mass ratio of NaOH-to-CME of 4.5-5.0, smelting temperature of 653-723 K, smelting time of 90-120 min. The models were validated experimentally in the optimum area, and the results demonstrate that these models are reliable and accurate in predicting the smelting process.
Key words:low-temperature alkaline smelting; waste printed circuit board; amphoteric metals; central composite design; conversion
