Formation of a new intermediate phase and its evolution toward θ’ during aging of pre-deformed Al-Cu alloys
来源期刊:JOURNAL OF MATERIALS SCIENCE TECHNOLOG2019年第5期
论文作者:Peipei Ma Chunhui Liu Ziyao Ma Lihua Zhan Minghui Huang
文章页码:885 - 890
摘 要:The frequent occurrence of hitherto unknown phase Pre-θ’-2 and unusual 1.5 cθ’ thick θ’ precipitate was observed by atomic-resolution scanning transmission electron microscopy in the well-studied Al-Cu alloys. This phenomenon is associated with heterogeneous precipitate nucleation and growth on preexisting dislocations introduced by slight deformation prior to aging. In this study, the precise structure details of Pre-θ’-2 was determined by atomic scale imaging, image simulation based on image forming theories and first principle calculations. Pre-θ’-2 has a well-defined ordered structure sandwiched between two 2 aAl(~1.5 cθ’) spaced Cu layers on {200}Alplanes. The strong structural similarities between Pre-θ’-2 and 1.5 cθ’ thick θ’ in terms of interfacial structure and thickness, coupled with energetic calculations and preliminary in-situ observations, lead us to propose a new precipitation path toward key strengthening phase θ’.
Peipei Ma1,Chunhui Liu1,2,Ziyao Ma2,Lihua Zhan1,2,Minghui Huang1,2
1. Light Alloy Research Institute of Central South University, State Key Laboratory of High-Performance Complex Manufacturing, Central South University2. School of Mechanical and Electrical Engineering, Central South University
摘 要:The frequent occurrence of hitherto unknown phase Pre-θ’-2 and unusual 1.5 cθ’ thick θ’ precipitate was observed by atomic-resolution scanning transmission electron microscopy in the well-studied Al-Cu alloys. This phenomenon is associated with heterogeneous precipitate nucleation and growth on preexisting dislocations introduced by slight deformation prior to aging. In this study, the precise structure details of Pre-θ’-2 was determined by atomic scale imaging, image simulation based on image forming theories and first principle calculations. Pre-θ’-2 has a well-defined ordered structure sandwiched between two 2 aAl(~1.5 cθ’) spaced Cu layers on {200}Alplanes. The strong structural similarities between Pre-θ’-2 and 1.5 cθ’ thick θ’ in terms of interfacial structure and thickness, coupled with energetic calculations and preliminary in-situ observations, lead us to propose a new precipitation path toward key strengthening phase θ’.
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