Membrane combination technic on treatment and reuse of high ammonia and salts wastewater in rare earth manufacture process
来源期刊:Journal of Rare Earths2010年第S1期
论文作者:张林楠 徐炳辉 龚济达 步天达
文章页码:501 - 503
摘 要:With the rapid development of rare earth industry in China,high NH3-N and high salts wastewater generated in rare earth manufacture process had caused serious environment pollution especially for surrounding water body.Traditional treatment processes were either incapable of reducing pollutants concentration to the levels regulated by law or prohibitively expensive and difficult to operate.In this paper,a hybrid process which integrated air stripping pretreatment and low pressure reverse osmosis(LPRO) was proposed to treat this wastewater containing high ammonia and salt.Mechanism of treatment and remediation of ammonia and salt polluted water body was investigated.Influences of temperature,pH,and air stripping time on removal ratio of ammonia efficiencies were also discussed.Relationship among trans-membrane pressure drop(ΔP),additions ratio,stability of membrane and the possibility of water reuse were studied.The results showed that removal ratio of ammonia after LPRO desalination process could reach up to 98%,fluoride amounted to more than 99% and desalt efficiencies reached up to 95%,and stripped gas ammonia could be effectively recovered.Water quality had been improved significantly to meet reuse or discharge standards.
张林楠1,2,徐炳辉1,龚济达3,步天达3
1. School of Science,Shenyang University of Technology2. School of Environmental Sciences and Engineering,Peking University3. School of Environmental and Ecological,Center Minzu University
摘 要:With the rapid development of rare earth industry in China,high NH3-N and high salts wastewater generated in rare earth manufacture process had caused serious environment pollution especially for surrounding water body.Traditional treatment processes were either incapable of reducing pollutants concentration to the levels regulated by law or prohibitively expensive and difficult to operate.In this paper,a hybrid process which integrated air stripping pretreatment and low pressure reverse osmosis(LPRO) was proposed to treat this wastewater containing high ammonia and salt.Mechanism of treatment and remediation of ammonia and salt polluted water body was investigated.Influences of temperature,pH,and air stripping time on removal ratio of ammonia efficiencies were also discussed.Relationship among trans-membrane pressure drop(ΔP),additions ratio,stability of membrane and the possibility of water reuse were studied.The results showed that removal ratio of ammonia after LPRO desalination process could reach up to 98%,fluoride amounted to more than 99% and desalt efficiencies reached up to 95%,and stripped gas ammonia could be effectively recovered.Water quality had been improved significantly to meet reuse or discharge standards.
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