Effect of Na2CO3 and CaCO3 on Coreduction Roasting of Blast Furnace Dust and High-phosphorus Oolitic Hematite
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2017年第3期
论文作者：曹允业 孙体昌 KOU Jue XU Chengyan GAO Enxia
文章页码：517 - 524
摘 要：Iron was recovered from blast furnace dust and high-phosphorus oolitic hematite in the presence of Na2CO3 and CaCO3 additives. The functions of Na2CO3 and CaCO3 during the coreduction roasting process were investigated by XRD and SEM-EDS analyses. Results indicate that these additives not only hinder the reduction of fluorapatite, CaCO3 also decreases the P content of direct reduced iron（DRI） by increasing the reduction alkalinity. P remains as fluorapatite in the slag, which can be removed by grinding and magnetic separation under optimal conditions. The Na2CO3 promotes hematite reduction and improves the iron recovery（εFe） by replacing the FeO from fayalite, which results in quick growth and aggregation of metallic iron and improvement of εFe in DRI. A DRI with 91.88 mass% Fe, and 0.065 mass% P can be achieved at a recovery of 87.86 mass% under the optimal condition.
曹允业，孙体昌，KOU Jue，XU Chengyan，GAO Enxia
School of Civil & Environmental Engineering, Key Laboratory of High-Efficient Mining and Safety of Metal Mines, Ministry of Education,University of Science and Technology Beijing
摘 要：Iron was recovered from blast furnace dust and high-phosphorus oolitic hematite in the presence of Na2CO3 and CaCO3 additives. The functions of Na2CO3 and CaCO3 during the coreduction roasting process were investigated by XRD and SEM-EDS analyses. Results indicate that these additives not only hinder the reduction of fluorapatite, CaCO3 also decreases the P content of direct reduced iron（DRI） by increasing the reduction alkalinity. P remains as fluorapatite in the slag, which can be removed by grinding and magnetic separation under optimal conditions. The Na2CO3 promotes hematite reduction and improves the iron recovery（εFe） by replacing the FeO from fayalite, which results in quick growth and aggregation of metallic iron and improvement of εFe in DRI. A DRI with 91.88 mass% Fe, and 0.065 mass% P can be achieved at a recovery of 87.86 mass% under the optimal condition.
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