Fabrication and Properties of Degradable PPC/EVOH/starch/CaCO3 Composites
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2008年第3期
论文作者：乔俊娟 孟跃中
文章页码：362 - 366
摘 要：Thermally stable and biodegradable composites from poly（propylene carbonate）（PPC）,poly （ethylene-co-vinyl alcohol）（EVOH）,starch and CaCO 3 were fabricated by melt blending.Differential scanning calorimetry（DSC）,differential thermal analysis/thermal gravimetric analysis（DTA/TGA）,tensile test and scanning electron microscope（SEM）were performed to investigate the miscibility,thermal behavior and tensile properties of the PPC/EVOH/Starch/CaCO 3 composites.DSC results indicate that the introduction of EVOH could improve the compatibility between PPC and starch to some extent because of the interfacial interaction between PPC and EVOH,leading to an increase in tensile strength.The tensile strength began to decrease when more starch was added due to the aggregation of starch particles.SEM examination showed the good interfacial bonding between the fillers and polymeric components.The incorporation of both EVOH and fillers can greatly increase the thermal stability of PPC matrix.The PPC/EVOH/Starch/CaCO 3 composites can be melt processed and can be used as a common biodegradable material for a wide application.
乔俊娟，孟跃中
摘 要：Thermally stable and biodegradable composites from poly（propylene carbonate）（PPC）,poly （ethylene-co-vinyl alcohol）（EVOH）,starch and CaCO 3 were fabricated by melt blending.Differential scanning calorimetry（DSC）,differential thermal analysis/thermal gravimetric analysis（DTA/TGA）,tensile test and scanning electron microscope（SEM）were performed to investigate the miscibility,thermal behavior and tensile properties of the PPC/EVOH/Starch/CaCO 3 composites.DSC results indicate that the introduction of EVOH could improve the compatibility between PPC and starch to some extent because of the interfacial interaction between PPC and EVOH,leading to an increase in tensile strength.The tensile strength began to decrease when more starch was added due to the aggregation of starch particles.SEM examination showed the good interfacial bonding between the fillers and polymeric components.The incorporation of both EVOH and fillers can greatly increase the thermal stability of PPC matrix.The PPC/EVOH/Starch/CaCO 3 composites can be melt processed and can be used as a common biodegradable material for a wide application.
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