Extraction of Metals from Boiler Slag by Sintering
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2009年第5期
论文作者：李进平 侯浩波
文章页码：736 - 741
摘 要：A new method of recycling aluminum and iron in boiler slag derived from plants that use coal as fuel was presented. The new method can integrate efficient extraction and reuse of the leached pellets together. An elemental analysis of aqueous solutions leached by sulfuric acid was conducted by the EDTA-Na2-ZnCl2 titration method, and the components and microstructures of the samples were examined by means of XRF, XRD and SEM. An aluminum extraction efficiency of 86.50% was achieved when the sintered pellets were leached using 4 mol·L-1 H2SO4 with solid/liquid ratio（m/V） of 1∶5 at 80 ℃ for 24 h. An iron extraction efficiency of 94.60% was achieved under the same condition for the maximum extraction efficiency of Al. The extraction efficiency of Al and Fe increased with temperature, leaching time and acidity. The concentration of alumina and iron hydroxide in the final product was determined to be 99.12% and 92.20% respectively. This product of alumina would be used directly for the production of metallic aluminum.
李进平1,2，侯浩波1
1. School of Resource and Environment Science, Wuhan University2. School of Environment and Urban Construction, Wuhan University of Science and Engineering
摘 要：A new method of recycling aluminum and iron in boiler slag derived from plants that use coal as fuel was presented. The new method can integrate efficient extraction and reuse of the leached pellets together. An elemental analysis of aqueous solutions leached by sulfuric acid was conducted by the EDTA-Na2-ZnCl2 titration method, and the components and microstructures of the samples were examined by means of XRF, XRD and SEM. An aluminum extraction efficiency of 86.50% was achieved when the sintered pellets were leached using 4 mol·L-1 H2SO4 with solid/liquid ratio（m/V） of 1∶5 at 80 ℃ for 24 h. An iron extraction efficiency of 94.60% was achieved under the same condition for the maximum extraction efficiency of Al. The extraction efficiency of Al and Fe increased with temperature, leaching time and acidity. The concentration of alumina and iron hydroxide in the final product was determined to be 99.12% and 92.20% respectively. This product of alumina would be used directly for the production of metallic aluminum.
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