Study on rare earth electrolyte of SDC-LSGM
来源期刊：Journal of Rare Earths2008年第2期
论文作者：徐丹 刘晓梅 朱成军 王德军 严端廷 王德涌 苏文辉
文章页码：241 - 244
摘 要：Ce0.85Sm0.15O1.925 （SDC） and La0.9Sr0.1Ga0.8Mg0.2O2.85 （LSGM） were synthesized using Glycine-Nitrate Process （GNP）, and the composite electrolytes were prepared by mixing SDC and LSGM. An X-ray diffraction pattern indicated that the mixture of SDC and LSGM consisted of their original phases after heating at 1450 oC for 10 h. The electronic conductivity of SDC-LSGM composite electrolytes were measured by direct current polarization method using Hebb-Wagner ion blocking cell at 700-800 oC in the oxygen partial pressure range of 10-6-10-20 MPa and compared with the results of SDC. Typical polarization curves, which were theoretically predicted, were observed on all the samples. The slopes of lgσe-lgPo2 plot for all the composite electrolytes agreed with the theoretically predicted value of -1/4 at some in- termediate oxygen partial pressures and -1/6 at low oxygen partial pressure. The electronic conductivity of SDC-LSGM composite electro- lytes decreased with the increase in LSGM content, whereas the ionic transport number ti of all the samples increased with the increase in LSGM content.
徐丹，刘晓梅，朱成军，王德军，严端廷，王德涌，苏文辉
摘 要：Ce0.85Sm0.15O1.925 （SDC） and La0.9Sr0.1Ga0.8Mg0.2O2.85 （LSGM） were synthesized using Glycine-Nitrate Process （GNP）, and the composite electrolytes were prepared by mixing SDC and LSGM. An X-ray diffraction pattern indicated that the mixture of SDC and LSGM consisted of their original phases after heating at 1450 oC for 10 h. The electronic conductivity of SDC-LSGM composite electrolytes were measured by direct current polarization method using Hebb-Wagner ion blocking cell at 700-800 oC in the oxygen partial pressure range of 10-6-10-20 MPa and compared with the results of SDC. Typical polarization curves, which were theoretically predicted, were observed on all the samples. The slopes of lgσe-lgPo2 plot for all the composite electrolytes agreed with the theoretically predicted value of -1/4 at some in- termediate oxygen partial pressures and -1/6 at low oxygen partial pressure. The electronic conductivity of SDC-LSGM composite electro- lytes decreased with the increase in LSGM content, whereas the ionic transport number ti of all the samples increased with the increase in LSGM content.
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