27Al MAS-NMR study of inorganic polymer formation at ambient temperature

来源期刊:中国有色金属学报(英文版)2011年第z1期

论文作者:Sang-Wook AHN Hee-Soo LEE Wan-Hee YANG Jung-Woo LEE Young-Keun JEONG

文章页码:182 - 187

Key words:inorganic polymer; amorphous; tetrahedral

Abstract: Inorganic polymers are a novel class of materials formed by the polymerization of silicon, aluminium and oxygen species to form an amorphous three-dimensional framework structure. The basis of this process is the alkaline solutions to induce a certain amount of Si and Al atoms to dissolve from a feedstock such as aluminosilicate. A study of 27Al MAS-NMR was carried out in an attempt to understand the reaction mechanism of the inorganic polymerization at ambient temperature. Scanning electron microscopy (SEM) and X-ray diffractometry (XRD) were also employed to establish the composition and microstructure of the inorganic polymerization. Specimens were prepared with different Al/Si mole ratios from the starting materials. The higher the Al content, the more sufficient the Al atoms that can combine with SiO4, and the longer the reaction time, the more the bonded Si—O—Al—O polymer structure, and then the higher the Al content, the fewer the octahedral Al with a uniform Si—O—Al—O structure in four directions, because four Al atoms are combined with SiO4, resulting in a uniform Si—O—Al—O structure in four directions. The results show that they have an amorphous microstructure.

有色金属在线官网  |   会议  |   在线投稿  |   购买纸书  |   科技图书馆

中南大学出版社 技术支持 版权声明   电话:0731-88830515 88830516   传真:0731-88710482   Email:administrator@cnnmol.com

互联网出版许可证:(署)网出证(京)字第342号   京ICP备17050991号-6      京公网安备11010802042557号