简介概要

Preparation and Photocatalytic Activity of Fluorine and Cerium Codoped Nano-TiO2 Powders

来源期刊:Journal of Rare Earths2007年第S1期

论文作者:李发堂 赵地顺 陈伟娜 商世臣 殷蓉

文章页码:146 - 149

摘    要:Nano-F-/Ce3+/TiO2 particles were prepared by hydrolysis of tetrabutyl titanate in a mixed CF3COOH-Ce(NO3)3-H2O solution. The photocatalytic decomposition of methylene blue in aqueous solution was used to evaluate their photocatalytic activities. The powders were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersion X-ray spectrum (EDS), and Brunauer-Emmett-Teller (BET) surface area analysis. The results showed that F- and Ce3+ were doped into TiO2. The appropriate content of fluorine and cerium were 2.0% and 1.0% (atom fraction) respectively. The codoped nano-F-/Ce3+/TiO2 particles had higher BET specific surface area, smaller crystallite size and higher photocatalytic activity than those of undoped TiO2 particles.

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Preparation and Photocatalytic Activity of Fluorine and Cerium Codoped Nano-TiO2 Powders

李发堂,赵地顺,陈伟娜,商世臣,殷蓉

摘 要:Nano-F-/Ce3+/TiO2 particles were prepared by hydrolysis of tetrabutyl titanate in a mixed CF3COOH-Ce(NO3)3-H2O solution. The photocatalytic decomposition of methylene blue in aqueous solution was used to evaluate their photocatalytic activities. The powders were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), energy dispersion X-ray spectrum (EDS), and Brunauer-Emmett-Teller (BET) surface area analysis. The results showed that F- and Ce3+ were doped into TiO2. The appropriate content of fluorine and cerium were 2.0% and 1.0% (atom fraction) respectively. The codoped nano-F-/Ce3+/TiO2 particles had higher BET specific surface area, smaller crystallite size and higher photocatalytic activity than those of undoped TiO2 particles.

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