One-pot Synthesis of Bio-inspired Layered Materials of 3D Graphene Network/Calcium Carbonate
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2017年第4期
论文作者：张晶 YAO Bin PING Hang YU Hongjian ZHANG Fan ZHANG Jinyong WANG Yucheng WANG Hao WANG Weimin 傅正义
文章页码：795 - 799
摘 要：A bio-inspired layered material of reduced graphene oxide（RGOs） and calcium carbonate was synthesized via a one-pot strategy in DMF/H2O mixed solvent. The experimental results show that the product is a layered material of wrinkled RGOs networks and micron-sized calcium carbonate particles with uniform granular diameter and homogeneous morphology, which are distributed between the layered gallery of the graphene scaffold. The polymorph and the morphology of the in-situ produced calcium carbonate particles can be manipulated by simply changing the temperature scheme. Besides, the graphene oxide was reduced to a certain extent, and the hierarchical wrinkles were generated in the RGOs layer by the in-situ formation of the calcium carbonate particles. This work provides a facile and controllable strategy for synthesizing layered material of RGOs and carbonates, and also presents a platform for making three-dimensional porous wrinkled RGOs networks.
张晶，YAO Bin，PING Hang，YU Hongjian，ZHANG Fan，ZHANG Jinyong，WANG Yucheng，WANG Hao，WANG Weimin，傅正义
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology
摘 要：A bio-inspired layered material of reduced graphene oxide（RGOs） and calcium carbonate was synthesized via a one-pot strategy in DMF/H2O mixed solvent. The experimental results show that the product is a layered material of wrinkled RGOs networks and micron-sized calcium carbonate particles with uniform granular diameter and homogeneous morphology, which are distributed between the layered gallery of the graphene scaffold. The polymorph and the morphology of the in-situ produced calcium carbonate particles can be manipulated by simply changing the temperature scheme. Besides, the graphene oxide was reduced to a certain extent, and the hierarchical wrinkles were generated in the RGOs layer by the in-situ formation of the calcium carbonate particles. This work provides a facile and controllable strategy for synthesizing layered material of RGOs and carbonates, and also presents a platform for making three-dimensional porous wrinkled RGOs networks.
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