溶液性质对岩矿超电势的影响及地质意义

来源期刊：中南大学学报(自然科学版)1997年第2期

论文作者：仇勇海 陈白珍

文章页码：7 - 10

关键词：溶液； 激发极化法； 超电势

Key words：solution； induced polarization； overpotential；

摘    要：黄铜矿标本超电势的实验结果表明：在 一定的电流密度下，溶液中氧化剂、还原剂含量愈少，超电势则愈大，在自来水、蒸馏水等介质中超电势达到极大值．作者根据反应活化能等理论对该现象作了解释．在野外地质条件下，石墨矿形成了强大的激电异常，而有些小而富的金属硫化矿未观测到明显的激电异常，这可以用围岩溶液性质的差异得到圆满解释

Abstract: Results of overpotential experiment of chalcopyrites sample indicate that: under the fixed current density, the less the oxidizer and agent content of solution, the higher the overpotential is. It reaches the maximum value in such mediums as tap water and distilled water. Based on the theory about activation energy of reaction, an interpretation of this pheomenon is given in the paper. Under the field condition, graphite deposit will cause high IP anomaly, but the anomaly of some small rich metallic sulphide deposits is too small to be observed. The phenomenon can be interpretated by the difference of enclosing rock solution property.