High-performance asymmetric supercapacitors based on reduced graphene oxide/polyaniline composite electrodes with sandwich-like structure
来源期刊：JOURNAL OF MATERIALS SCIENCE TECHNOLOG2018年第7期
论文作者：Jun Ma Shaochun Tang Junaid Ali Syed Dongyun Su Xiangkang Meng
文章页码：1103 - 1109
摘 要：The sandwich-like structure of reduced graphene oxide/polyaniline（RGO/PANI） hybrid electrode was prepared by electrochemical deposition. Both the voltage windows and electrolytes for electrochemical deposition of PANI and RGO were optimized. In the composites, PANI nanofibers were anchored on the surface of the RGO sheets, which avoids the re-stacking of neighboring sheets. The RGO/PANI composite electrode shows a high specific capacitance of 466 F/g at 2 m A/cm2 than that of previously reported RGO/PANI composites. Asymmetric flexible supercapacitors applying RGO/PANI as positive electrode and carbon fiber cloth as negative electrode can be cycled reversibly in the high-voltage region of 0–1.6 V and displays intriguing performance with a maximum specific capacitance of 35.5 m F cm-2. Also, it delivers a high energy density of 45.5 m W h cm-2 at power density of 1250 m W cm-2. Furthermore, the asymmetric device exhibits an excellent long cycle life with 97.6% initial capacitance retention after 5000 cycles.Such composite electrode has a great potential for applications in flexible electronics, roll-up display,and wearable devices.
Jun Ma1,2，Shaochun Tang1，Junaid Ali Syed1，Dongyun Su3，Xiangkang Meng1
1. Institute of Materials Engineering, National Laboratory of Solid State Microstructures, and College of Engineering and Applied Sciences, Nanjing University2. School of Mechatronics & Traffic Engineering, Nantong College of Science and Technology3. College of Mechanical Engineering, Nantong Vocational University
摘 要：The sandwich-like structure of reduced graphene oxide/polyaniline（RGO/PANI） hybrid electrode was prepared by electrochemical deposition. Both the voltage windows and electrolytes for electrochemical deposition of PANI and RGO were optimized. In the composites, PANI nanofibers were anchored on the surface of the RGO sheets, which avoids the re-stacking of neighboring sheets. The RGO/PANI composite electrode shows a high specific capacitance of 466 F/g at 2 m A/cm2 than that of previously reported RGO/PANI composites. Asymmetric flexible supercapacitors applying RGO/PANI as positive electrode and carbon fiber cloth as negative electrode can be cycled reversibly in the high-voltage region of 0–1.6 V and displays intriguing performance with a maximum specific capacitance of 35.5 m F cm-2. Also, it delivers a high energy density of 45.5 m W h cm-2 at power density of 1250 m W cm-2. Furthermore, the asymmetric device exhibits an excellent long cycle life with 97.6% initial capacitance retention after 5000 cycles.Such composite electrode has a great potential for applications in flexible electronics, roll-up display,and wearable devices.
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