Research of Luminescence Properties on MO-RE2 O3 -B2 O3:Eu, Mn(M=Mg, Ca, Sr; RE=Y, La, Gd)
来源期刊：JOURNAL OF RARE EARTHS2004年增刊第1期
论文作者：Liang Zhongyi HE Dawei Shi Yanning
Key words：luminescence; long wave-UV excitation; phosphor; rare earths;
Abstract: A series of phosphor of MO-RE2 O3-B2 O3: Eu, Mn ( M = Mg, Ca, Sr; RE = Y, La, Gd) were prepared and studied.Excitation spectra exhibited high absorption in UV region (370 ～ 400 nm).There existed two valence states for europium ions Eu2+ and Eu 3+, the broad emission band peaking at 515 nm correspond to the 5d-4f emission transition of Eu2+ , the sharp emission peaking at 590 and 610 nm correspond to the 5D0→7FJ(J = 1,2,3,4) emission transition of Eu 3 + By the introduction of Mg and Y into MO-RE2O3-B2O3: Eu, blue-green emission was restrained ultimately and red emission peaking at 610 nm was enhanced strongly, intensity and colorimetric purity of red light were both enhanced.Furthermore, Mg1-xSrxO-Y2O3-B2O3: Eu was also researched, the introduction of Sr into MgO-Y2O3-B2O3:Eu gives rise to a shift to longer wavelengths of the position of the excitation peak, and the emission spectra varies with the increasing of x simultaneously.
Liang Zhongyi1，HE Dawei1，Shi Yanning1
(1.Ministry of Education Key Lab, Lab of Materials for Information Storage and Display, Institute of Photoelectron Technology, Northern Jiao Tong University, Beijing 100044, China)
Abstract:A series of phosphor of MO-RE2 O3-B2 O3: Eu, Mn ( M = Mg, Ca, Sr; RE = Y, La, Gd) were prepared and studied.Excitation spectra exhibited high absorption in UV region (370 ～ 400 nm).There existed two valence states for europium ions Eu2+ and Eu 3+, the broad emission band peaking at 515 nm correspond to the 5d-4f emission transition of Eu2+ , the sharp emission peaking at 590 and 610 nm correspond to the 5D0→7FJ(J = 1,2,3,4) emission transition of Eu 3 + By the introduction of Mg and Y into MO-RE2O3-B2O3: Eu, blue-green emission was restrained ultimately and red emission peaking at 610 nm was enhanced strongly, intensity and colorimetric purity of red light were both enhanced.Furthermore, Mg1-xSrxO-Y2O3-B2O3: Eu was also researched, the introduction of Sr into MgO-Y2O3-B2O3:Eu gives rise to a shift to longer wavelengths of the position of the excitation peak, and the emission spectra varies with the increasing of x simultaneously.
Key words:luminescence; long wave-UV excitation; phosphor; rare earths;
【全文内容正在添加中】
