Fabrication of flower-like mesoporous TiO2 hierarchical spheres with ordered stratified structure as an anode for lithium-ion batteries
来源期刊：JOURNAL OF MATERIALS SCIENCE TECHNOLOG2019年第4期
论文作者：Yujie Zheng Bingjie Liu Pei Cao Hui Huang Jing Zhang Guowei Zhou
文章页码：667 - 673
摘 要：In this study, flower-like mesoporous TiO2 hierarchical spheres（FMTHSs） with ordered stratified structure and TiO2 nanoparticles（TNPs） were synthesized via a facile solvothermal route and an etching reaction. Multilamellar vesicles（MTSVs） and unilamellar TiO2/SiO2 vesicles（UTSVs） were prepared using cetyltrimethylammonium bromide and didodecyldimethylammonium bromide as structure-directing agents under different solvothermal conditions. FMTHSs and TNPs were obtained from the etching reactions of MTSVs and UTSVs, respectively, in an alkaline system. FMTHSs display flower-like, ordered stratified structures on each petal. The thickness of the ordered stratified structure is approximately3–6 nm, and the number of layers is approximately 2–4. The FMTHSs2 electrode exhibits the first discharge capacity of 212.4 m A h g-1 at 0.2 C, which is higher than that of TNPs electrode(167.6 mA h g-1).The discharge specific capacity of FMTHSs2 electrode after 200 cycles at 1 C is 105.9 mA h g-1, which is higher than that of TNPs electrode(52.2 mA h g-1) after the same number of cycles. The outstanding performance of FMTHSs2 electrode is attributed to the advantages of FMTHSs. In particular, their own stratified structure can provide additional active sites for reactions. The hierarchical structure can provide short diffusion length for Li+, large electrolyte–electrode contact area, and superior accommodation of the strain of Li+intercalation/deintercalation.
Yujie Zheng，Bingjie Liu，Pei Cao，Hui Huang，Jing Zhang，Guowei Zhou
Key Laboratory of Fine Chemicals in Universities of Shandong,School of Chemistry and Pharmaceutical Engineering,Qilu University of Technology (Shandong Academy of Sciences)
摘 要：In this study, flower-like mesoporous TiO2 hierarchical spheres（FMTHSs） with ordered stratified structure and TiO2 nanoparticles（TNPs） were synthesized via a facile solvothermal route and an etching reaction. Multilamellar vesicles（MTSVs） and unilamellar TiO2/SiO2 vesicles（UTSVs） were prepared using cetyltrimethylammonium bromide and didodecyldimethylammonium bromide as structure-directing agents under different solvothermal conditions. FMTHSs and TNPs were obtained from the etching reactions of MTSVs and UTSVs, respectively, in an alkaline system. FMTHSs display flower-like, ordered stratified structures on each petal. The thickness of the ordered stratified structure is approximately3–6 nm, and the number of layers is approximately 2–4. The FMTHSs2 electrode exhibits the first discharge capacity of 212.4 m A h g-1 at 0.2 C, which is higher than that of TNPs electrode(167.6 mA h g-1).The discharge specific capacity of FMTHSs2 electrode after 200 cycles at 1 C is 105.9 mA h g-1, which is higher than that of TNPs electrode(52.2 mA h g-1) after the same number of cycles. The outstanding performance of FMTHSs2 electrode is attributed to the advantages of FMTHSs. In particular, their own stratified structure can provide additional active sites for reactions. The hierarchical structure can provide short diffusion length for Li+, large electrolyte–electrode contact area, and superior accommodation of the strain of Li+intercalation/deintercalation.
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