Synthesis and Characterization of A Dinuclear Europium Complex
来源期刊：Journal of Rare Earths2007年第S1期
论文作者：周永慧 郑佑轩 Gianluca Accorsi Nicola Ammaroli
文章页码：41 - 44
摘 要：A dinuclear Eu（Ⅲ） complex Eu2（DBM）6TPPD （Hexa（dibenzoyl-methanido）-（N, N, N, N-tetra（2-pyridyl）-1, 4-phenylenediamine）-dieuropium（Ⅲ）） was synthesized by employing DBM （dibenzoylmethane） and TPPD （N, N, N, N-Tetra（2-pyridyl）-1, 4-phenyl-enediamine） as sensitizing ligands for the Eu（Ⅲ） ion and a bridging ligand, respectively. The analysis of the absorption, excitation, and emission spectra of the dinuclear complex along with a comparison with analogous mononuclear complex containing the same β-diketone ligands and 1, 10-phenanthroline （phen） suggests that the dinuclear complex follows the luminescence mechanism of general Ln（Ⅲ） complexes.
周永慧，郑佑轩，Gianluca Accorsi，Nicola Ammaroli
摘 要：A dinuclear Eu（Ⅲ） complex Eu2（DBM）6TPPD （Hexa（dibenzoyl-methanido）-（N, N, N, N-tetra（2-pyridyl）-1, 4-phenylenediamine）-dieuropium（Ⅲ）） was synthesized by employing DBM （dibenzoylmethane） and TPPD （N, N, N, N-Tetra（2-pyridyl）-1, 4-phenyl-enediamine） as sensitizing ligands for the Eu（Ⅲ） ion and a bridging ligand, respectively. The analysis of the absorption, excitation, and emission spectra of the dinuclear complex along with a comparison with analogous mononuclear complex containing the same β-diketone ligands and 1, 10-phenanthroline （phen） suggests that the dinuclear complex follows the luminescence mechanism of general Ln（Ⅲ） complexes.
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