Syntheses and Characterization of Binuclear Complexes Tb1-xEux（TTA）3 Phen
来源期刊：Journal of Rare Earths2007年第3期
论文作者：吕玉光 张敬畅 曹维良 张福俊 徐征
文章页码：296 - 301
摘 要：Rare earth ternary complexes Tb1-xEux（TTA）3Phen（x=0,0.25,0.5,0.75,1.0）were synthesized and characterized by DTA-TG,XRD and infrared（IR）.The photophysical properties of these complexes were studied in detail using ultraviolet absorption spectra and fluorescent spectra.Ultraviolet absorption showed that the energy absorption of the complexes mostly came from ligands.Infrared spectra of Tb1-xEux（TTA）3Phen complexes were similar to the pure complexes.TG curves proved that the complexes were stable.Tb3+ emission was almost quenched and the Eu3+ emission was enhanced by codoping the complexes.The Tb3+ ion acted as an energy transfer bridge that helped energy transfer from poly(N-vinylcar-bazole（PVK）to Eu3+.In addition,their PL and EL properties were systematically studied.
吕玉光，张敬畅，曹维良，张福俊，徐征
摘 要：Rare earth ternary complexes Tb1-xEux（TTA）3Phen（x=0,0.25,0.5,0.75,1.0）were synthesized and characterized by DTA-TG,XRD and infrared（IR）.The photophysical properties of these complexes were studied in detail using ultraviolet absorption spectra and fluorescent spectra.Ultraviolet absorption showed that the energy absorption of the complexes mostly came from ligands.Infrared spectra of Tb1-xEux（TTA）3Phen complexes were similar to the pure complexes.TG curves proved that the complexes were stable.Tb3+ emission was almost quenched and the Eu3+ emission was enhanced by codoping the complexes.The Tb3+ ion acted as an energy transfer bridge that helped energy transfer from poly(N-vinylcar-bazole（PVK）to Eu3+.In addition,their PL and EL properties were systematically studied.
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