Effects of cupric ions on the corrosion behavior of aluminum alloy 5A02 in ethylene glycol–water solution
来源期刊：International Journal of Minerals Metallurgy and Materials2017年第4期
论文作者：Shu-lun Gao Mei Yu Jian-hua Liu Bing Xue Song-mei Li
文章页码：423 - 431
摘 要：The effects of cupric ions on the corrosion behavior of aluminum alloy 5A02 in ethylene glycol–water solutions were studied by potentiodynamic polarization,electrochemical noise（EN）,and complementary techniques including scanning electron microscopy（SEM）,atomic force microscopy（AFM）,and X-ray photoelectron spectroscopy（XPS）. A positive corrosion potential and increased corrosion current were observed due to the deposition of copper. The results demonstrate that the main corrosion type was pitting and the increasing cupric ion concentration augmented the pitting density. The pits became larger and deeper as a result of the embedment of copper into the surface of the alloy. Cupric ions were preferentially deposited at the defects around the secondary phase,leading to the formation of Al–Cu microgalvanic couples,which increased the corrosion rate. The corrosion rate gradually reached a stable value as the concentration of cupric ions was increased beyond 10 mmol/L.
Shu-lun Gao，Mei Yu，Jian-hua Liu，Bing Xue，Song-mei Li
School of Materials Science and Engineering,Beihang University
摘 要：The effects of cupric ions on the corrosion behavior of aluminum alloy 5A02 in ethylene glycol–water solutions were studied by potentiodynamic polarization,electrochemical noise（EN）,and complementary techniques including scanning electron microscopy（SEM）,atomic force microscopy（AFM）,and X-ray photoelectron spectroscopy（XPS）. A positive corrosion potential and increased corrosion current were observed due to the deposition of copper. The results demonstrate that the main corrosion type was pitting and the increasing cupric ion concentration augmented the pitting density. The pits became larger and deeper as a result of the embedment of copper into the surface of the alloy. Cupric ions were preferentially deposited at the defects around the secondary phase,leading to the formation of Al–Cu microgalvanic couples,which increased the corrosion rate. The corrosion rate gradually reached a stable value as the concentration of cupric ions was increased beyond 10 mmol/L.
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