Preparation of Monodisperse Spherical SiO₂ by Microwave Hydrothermal Method and Kinetics of Dehydrated Hydroxyl

Xiaoyi Shen1), Yuchun Zhai1), Yang Sun1,2) and Huimin Gu1) 1) School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China 2) Educational Department of Liaoning Province, Shenyang 110032, China

摘 要：Monodisperse spherical SiO2 particles were successfully synthesized in 2-propanol-H2O-NH3 system by the microwave hydrothermal method using ammonia as catalyst. To investigate the influences on the size of spherical SiO2 particles, factors such as ammonia concentration, reaction temperature, stirring intensity and reactants mol ratio have been studied. The orthogonal experiments were carried out. The as-prepared SiO2 particles were characterized by X-ray diffraction （XRD）, transmission electron microscopy （TEM）, Fourier transform infrared spectroscopy （FTIR） and differential thermal analysis （DTA）. The results indicated that the size of SiO2 particles increased greatly with the increase in ammonia concentration, temperature and reactants mol ratio, but increased slightly with the increase in stirring intensity. Monodisperse spherical SiO2 particles were amorphous with perfect sphere and uniform size. Hydroxyl was detected in SiO2. Kinetic parameters were calculated, and finally the reaction rate equation of dehydrated hydroxyl was obtained.

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