3D Interconnected MoO2 Nanocrystals on Nickel Foam as Binder-free Anode for Li-ion Batteries
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2018年第6期
论文作者：祁琰媛 ZHOU Bo ZHENG Shenbo YANG Xue JIN Wei
文章页码：1315 - 1322
摘 要：MoO2 nanocrystals（NCs） on Ni foam were simply synthesized via a facile hydrothermal method and a dip-coating method. It was worth noting that ultrafine interconnected MoO2 nanocrystals（about 10 nm） were uniformly anchored on Ni foam to fabricate a particular three-dimensional architecture, which may provide more active sites and shorter transmission pathways for lithium ions. As binder-free anode, MoO2 NCs on Ni foam deliver a high initial discharge capacity of 990 mAh·g-1 and retain a reversible capacity of 924 mAh· g（-1） after 100 cycles at a current density of 0.1 C. More importantly, when the current density returns from 2 C to 0.1 C, the capacity recovers to 910 mAh·g（-1）（about 92% of the original high capacity）, suggesting excellent cycling stability and rate capability. The particular 3 D electrode as binder-free anode makes it a promising anode candidate for high-performance lithium-ion batteries.
祁琰媛1，ZHOU Bo2，ZHENG Shenbo2，YANG Xue2，JIN Wei2
1. Center for Materials Research and Analysis, Wuhan University of Technology2. School of Materials Science and Engineering, Wuhan University of Technology
摘 要：MoO2 nanocrystals（NCs） on Ni foam were simply synthesized via a facile hydrothermal method and a dip-coating method. It was worth noting that ultrafine interconnected MoO2 nanocrystals（about 10 nm） were uniformly anchored on Ni foam to fabricate a particular three-dimensional architecture, which may provide more active sites and shorter transmission pathways for lithium ions. As binder-free anode, MoO2 NCs on Ni foam deliver a high initial discharge capacity of 990 mAh·g-1 and retain a reversible capacity of 924 mAh· g（-1） after 100 cycles at a current density of 0.1 C. More importantly, when the current density returns from 2 C to 0.1 C, the capacity recovers to 910 mAh·g（-1）（about 92% of the original high capacity）, suggesting excellent cycling stability and rate capability. The particular 3 D electrode as binder-free anode makes it a promising anode candidate for high-performance lithium-ion batteries.
关键词：
