Reactive sintering of B4C-TaB2 ceramics via carbide boronizing:Reaction process, microstructure and mechanical properties
来源期刊：JOURNAL OF MATERIALS SCIENCE TECHNOLOG2019年第12期
论文作者：Junfeng Gu Ji Zou Peiyan Ma Hao Wang Jinyong Zhang Weimin Wang Zhengyi Fu
文章页码：2840 - 2850
摘 要：Carbide boronizing is a promising approach to obtain fine grained boron carbide based ceramics with improved mechanical properties. In this work, reaction process, microstructural characteristics and mechanical properties of BxC-TaB2（x = 3.7, 4.9, 7.1） ceramics were comprehensively investigated via this method. Dense BxC-TaB2 ceramics with refined microstructure were obtained from submicro tantalum carbide and boron powder mixtures at 1800?C/50 MPa/5 min by spark plasma sintering. The stoichiometry of boron carbide was determined from lattice parameters and Raman shift. It was found that uniformly distributed TaB2 grains in the BxC matrix is favor of the densification process and restricting grain growth.Besides, planar defects with high density were observed from the as-formed B7.1 C grains and transient stress was considered to contribute to the densification involved with plastic deformation. Microstructural observations indicate the dissolution of oxygen in the TaB2 lattice and most of the B7.1 C/TaB2 phase boundaries were clean. Owing to the highly faulted structure and finer grain size, as-obtained BxC-TaB2 ceramics exhibit high Vickers hardness（33.3–34.4 GPa at 9.8 N） and relatively high flexural strength ranging from 440 to 502 MPa.
Junfeng Gu1，Ji Zou1,2，Peiyan Ma3，Hao Wang1，Jinyong Zhang1，Weimin Wang1，Zhengyi Fu1
1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology2. School of Metallurgy and Materials, University of Birmingham3. School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology
摘 要：Carbide boronizing is a promising approach to obtain fine grained boron carbide based ceramics with improved mechanical properties. In this work, reaction process, microstructural characteristics and mechanical properties of BxC-TaB2（x = 3.7, 4.9, 7.1） ceramics were comprehensively investigated via this method. Dense BxC-TaB2 ceramics with refined microstructure were obtained from submicro tantalum carbide and boron powder mixtures at 1800?C/50 MPa/5 min by spark plasma sintering. The stoichiometry of boron carbide was determined from lattice parameters and Raman shift. It was found that uniformly distributed TaB2 grains in the BxC matrix is favor of the densification process and restricting grain growth.Besides, planar defects with high density were observed from the as-formed B7.1 C grains and transient stress was considered to contribute to the densification involved with plastic deformation. Microstructural observations indicate the dissolution of oxygen in the TaB2 lattice and most of the B7.1 C/TaB2 phase boundaries were clean. Owing to the highly faulted structure and finer grain size, as-obtained BxC-TaB2 ceramics exhibit high Vickers hardness（33.3–34.4 GPa at 9.8 N） and relatively high flexural strength ranging from 440 to 502 MPa.
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