Corrosion property of copperized layer on Zr formed by double glow plasma surface alloying technique
来源期刊:Rare Metals2016年第9期
论文作者:Jian-Qing Wang Hong-Bo Yang Bing Zhang Han-Long Lin Bao Chen Qin Jing
文章页码:711 - 717
摘 要:Zr and its alloys have excellent mechanical properties as new structural material,but in specific application environment,its corrosion resistance still needs to be further explored.In this work,double glow plasma surface alloying technique was used for copperizing on pure Zr surface.Besides,X-ray diffraction(XRD),scanning electron microscope(SEM) and energy dispersion spectrum(EDS) were employed to characterize the samples.Furthermore,research was also conducted on the polarization curve of the samples in different solutions.Copperizing on surface can improve corrosion resistance of pure Zr in 3.5 % Na Cl and 0.5 moláL-1Na OH solutions.Especially in 0.5 moláL-1Na OH solution,the corrosion resistance can achieve significant improvement.However,copperizing has no influence on the improvement of corrosion resistance of pure Zr in 0.5 moláL-1H2SO4 solution.The results may provide new insight into way for improving the corrosion property of zirconium alloys.
Jian-Qing Wang,Hong-Bo Yang,Bing Zhang,Han-Long Lin,Bao Chen,Qin Jing
State Key Laboratory of Metastable Materials Science and Technology,Yanshan University
摘 要:Zr and its alloys have excellent mechanical properties as new structural material,but in specific application environment,its corrosion resistance still needs to be further explored.In this work,double glow plasma surface alloying technique was used for copperizing on pure Zr surface.Besides,X-ray diffraction(XRD),scanning electron microscope(SEM) and energy dispersion spectrum(EDS) were employed to characterize the samples.Furthermore,research was also conducted on the polarization curve of the samples in different solutions.Copperizing on surface can improve corrosion resistance of pure Zr in 3.5 % Na Cl and 0.5 moláL-1Na OH solutions.Especially in 0.5 moláL-1Na OH solution,the corrosion resistance can achieve significant improvement.However,copperizing has no influence on the improvement of corrosion resistance of pure Zr in 0.5 moláL-1H2SO4 solution.The results may provide new insight into way for improving the corrosion property of zirconium alloys.
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