简介概要

Preparation and conductivity of nanocrystalline rare earth mixed oxides SmFe1-x,CoxO3-δ

来源期刊:Rare Metals2002年第3期

论文作者:REN Yinzhe, LIU Erbao WANG Jianying, and WANG Yuxian Department of Chemistry, Shanxi Normal University, Linfen , China Linfen Normal College of Shanxi Normal University, Linfen , China

文章页码:190 - 192

摘    要:<正>Nanocrystalline rare earth mixed oxides SmFe1-xCoxO3-δ were prepared by sol-gel method at 1 073 K for 2 h calcination and characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). The results show that SmFe1-xCoxO3-δ has the structure of perovskite type. The conductivity of the materials increases with the temperature rising and the maximum conductivity at 1 073 K is 2.6 S/cm with the best mole ratio of Fe3+ to Co3+ being 1 : 4. This kind of oxide is a conductive ceramic material by means of conduction of electron and oxygen anion.

详情信息展示

Preparation and conductivity of nanocrystalline rare earth mixed oxides SmFe1-x,CoxO3-δ

REN Yinzhe, LIU Erbao WANG Jianying, and WANG Yuxian Department of Chemistry, Shanxi Normal University, Linfen 041004, China Linfen Normal College of Shanxi Normal University, Linfen 041004, China

摘 要:<正>Nanocrystalline rare earth mixed oxides SmFe1-xCoxO3-δ were prepared by sol-gel method at 1 073 K for 2 h calcination and characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). The results show that SmFe1-xCoxO3-δ has the structure of perovskite type. The conductivity of the materials increases with the temperature rising and the maximum conductivity at 1 073 K is 2.6 S/cm with the best mole ratio of Fe3+ to Co3+ being 1 : 4. This kind of oxide is a conductive ceramic material by means of conduction of electron and oxygen anion.

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