Preparation of CuO-CoO-MnO/SiO2 Nanocomposite Aerogels as Catalyst Carriers and Their Application in the Synthesis of Diphenyl Carbonate
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2011年第4期
论文作者：赵越卿
文章页码：595 - 599
摘 要：CuO-CoO-MnO/SiO2 nanocomposite aerogels were prepared by using tetraethyl orthosilicate （TEOS） as Si source, and aqueous solution of Cu, Co and Mn acetates as transition metal sources via sol-gel process and supercritical drying （SCD） technique. The effect of synthesis conditions on gelation was investigated. Moreover, the composition of the CuO-CoO-MnO/SiO2 nanocomposite aerogels was characterized by electron dispersive spectroscopy （EDS） and X-ray photoelectron spectroscopy （XPS）, and the specific surface area of the nanocomposite aerogels was determined by the Brunauer-Emmett-Teller （BET） method. Diphenyl carbonate （DPC） as the product was analyzed by gas chromatography （GC）. The experimental results show that the range of optimal temperature for gelation is 30-45 ℃, and the pH is 3.0-4.5. CuO-CoO-MnO/SiO2 nanocomposite aerogels are porous with a specific surface area of 384.9-700.6 m2/g. Compared to CO2 SCD, ethanol SCD is even favorable to the formation of aerogel with high specific surface area. The transition metals content in the nanocomposite aerogels can be controlled to be 0.71at%-13.77at%. With CuO-CoO-MnO/SiO2 nanocomposite aerogels as catalyst carrier, the yield of DPC is in direct proportion to the atomic fraction of transition metals in the nanocomposite aerogels, and it is up to 26.31 mass%, which is much higher than that via other porous carriers.
赵越卿
School of Light Industry, Hebei United University
摘 要：CuO-CoO-MnO/SiO2 nanocomposite aerogels were prepared by using tetraethyl orthosilicate （TEOS） as Si source, and aqueous solution of Cu, Co and Mn acetates as transition metal sources via sol-gel process and supercritical drying （SCD） technique. The effect of synthesis conditions on gelation was investigated. Moreover, the composition of the CuO-CoO-MnO/SiO2 nanocomposite aerogels was characterized by electron dispersive spectroscopy （EDS） and X-ray photoelectron spectroscopy （XPS）, and the specific surface area of the nanocomposite aerogels was determined by the Brunauer-Emmett-Teller （BET） method. Diphenyl carbonate （DPC） as the product was analyzed by gas chromatography （GC）. The experimental results show that the range of optimal temperature for gelation is 30-45 ℃, and the pH is 3.0-4.5. CuO-CoO-MnO/SiO2 nanocomposite aerogels are porous with a specific surface area of 384.9-700.6 m2/g. Compared to CO2 SCD, ethanol SCD is even favorable to the formation of aerogel with high specific surface area. The transition metals content in the nanocomposite aerogels can be controlled to be 0.71at%-13.77at%. With CuO-CoO-MnO/SiO2 nanocomposite aerogels as catalyst carrier, the yield of DPC is in direct proportion to the atomic fraction of transition metals in the nanocomposite aerogels, and it is up to 26.31 mass%, which is much higher than that via other porous carriers.
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