Study on Extracting Rare Earth from Sulfate System by Long-Chain Fatty Acid
来源期刊:JOURNAL OF RARE EARTHS2004年增刊第1期
论文作者:ZHAO Zengqi Xu Yanhui Liu Quansheng
Key words:extraction; long-chain fatty acid; rare earths;
Abstract: The extraction of rare earths by long-chain fatty acid in kerosene from sulphate system was described.It was demonstrated from the experimental results that the ratio of kerosene: fatty acid: isooctanol = 55 : 30: 15 ( V/V),By the saturation capability method and the slope method, the extracted reaction mechanism of the extraction of rare earth was studied.It is shown that the extraction reaction conform to the cation exchange reaction mechanism.The extracted sequence of rare earth was determined in this system and it is shown that there is no tetrad effect and the position of yttrium is between lanthanum and cerium.
ZHAO Zengqi1,Xu Yanhui1,Liu Quansheng2
(1.Baotou Research Institute of Rare Earth, Baotou 014010, China;
2.Inner Mongolia Polytechnic University, Huhehaote 010062, China)
Abstract:The extraction of rare earths by long-chain fatty acid in kerosene from sulphate system was described.It was demonstrated from the experimental results that the ratio of kerosene: fatty acid: isooctanol = 55 : 30: 15 ( V/V),By the saturation capability method and the slope method, the extracted reaction mechanism of the extraction of rare earth was studied.It is shown that the extraction reaction conform to the cation exchange reaction mechanism.The extracted sequence of rare earth was determined in this system and it is shown that there is no tetrad effect and the position of yttrium is between lanthanum and cerium.
Key words:extraction; long-chain fatty acid; rare earths;
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