Development of calcium coke for CaC₂ production using calcium carbide slag and coking coal

Xu-zhong Gong^1,2,3，Jun-qiang Zhang¹，Zhi Wang^1,3，Dong Wang^1,3，Jun-hao Liu^1,3，Xiao-dong Jing^1,3，Guo-yu Qian^1,3

1. Key Laboratory of Green Process and Engineering, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences2. Chemical Engineering School, University of Chinese Academy of Sciences

摘 要：A type of calcium coke was developed for use in the oxy-thermal process of calcium carbide production.The calcium coke was prepared by the co-pyrolysis of coking coal and calcium carbide slag, which is a solid waste generated from the chlor-alkali industry.The characteristics of the calcium cokes under different conditions were analyzed experimentally and theoretically.The results show that the thermal strength of calcium coke increased with the increase in the coking coal proportion, and the waterproof property of calcium coke also increased with increased carbonation time.The calcium coke can increase the contact area of calcium and carbon in the calcium carbide production process.Furthermore, the pore structure of the calcium coke can enhance the diffusion of gas inside the furnace, thus improving the efficiency of the oxy-thermal technology.

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