Experimental assessment of a plasma-catalyst hybrid reformer for hydrogen production via partial oxidation of dimethyl ether
来源期刊：中南大学学报(英文版)2014年第5期
论文作者：SONG Ling-jun(宋凌珺) LI Xing-hu(李兴虎)
文章页码：1956 - 1960
Key words：spark discharge plasma; hybrid; reforming; hydrogen production; dimethyl ether
Abstract: In this work, hydrogen is produced from partial oxidation reforming of dimethyl ether (DME) by a plasma-catalyst hybrid reformer under atmospheric pressure. The plasma-catalyst hybrid reformer which includes both plasma and catalyst reactors is designed. A spark discharge is used as a non-equilibrium plasma source, and it is used to ionize the mixture of DME and air. The performances of the reformer are characterized experimentally in terms of gas concentrations, hydrogen yield, DME conversion ratio, and specific energy consumption. The effects of discharge frequency, reaction temperature, air-to-DME ratio and space velocity are investigated. The experimental results show that the plasma-catalyst hybrid reformer enhances hydrogen yield when reaction temperature drops below 620 °C. At 450 °C, hydrogen yield of hybrid reforming is almost three times that of catalyst reforming. When space velocity is 510 h-1, hydrogen yield is 67.7%, and specific energy consumption is 12.2 kJ/L-H2.
SONG Ling-jun(宋凌珺), LI Xing-hu(李兴虎)
(School of Transportation Science and Engineering, Beihang University, Beijing 100191, China)
Abstract:In this work, hydrogen is produced from partial oxidation reforming of dimethyl ether (DME) by a plasma-catalyst hybrid reformer under atmospheric pressure. The plasma-catalyst hybrid reformer which includes both plasma and catalyst reactors is designed. A spark discharge is used as a non-equilibrium plasma source, and it is used to ionize the mixture of DME and air. The performances of the reformer are characterized experimentally in terms of gas concentrations, hydrogen yield, DME conversion ratio, and specific energy consumption. The effects of discharge frequency, reaction temperature, air-to-DME ratio and space velocity are investigated. The experimental results show that the plasma-catalyst hybrid reformer enhances hydrogen yield when reaction temperature drops below 620 °C. At 450 °C, hydrogen yield of hybrid reforming is almost three times that of catalyst reforming. When space velocity is 510 h-1, hydrogen yield is 67.7%, and specific energy consumption is 12.2 kJ/L-H2.
Key words:spark discharge plasma; hybrid; reforming; hydrogen production; dimethyl ether
