简介概要

Kinetics of iron removal from metallurgical grade silicon with pressure leaching

来源期刊:Rare Metals2011年第6期

论文作者:YU Zhanlianga, b, c, XIE Keqianga, MA Wenhuia, ZHOU Yanga, XIE Gangb, c, and DAI Yongniana a National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming , China b Technology Center of Yunnan Metallurgy Group Co., Kunming , China c Kunming Metallurgy Research Institute, Kunming , China

文章页码:688 - 694

摘    要:In this paper, the kinetics of pressure leaching for purification of metallurgical grade silicon with hydrochloric acid was investigated. The effects of particle size, temperature, total pressure, and concentration of hydrochloric acid on the kinetics and mechanism of iron removal were studied. It was found that the reaction kinetic model followed the shrinking core model, and the apparent activation energy of the leaching reaction was 46.908 kJ/mol. And the apparent reaction order of iron removal with pressure leaching was 0.899. The kinetic equation was ob-tained and the mathematical model of iron removal from metallurgical grade silicon (MG-Si) was given as follows: 1-2/3x-(1-x)2/3=exp(5.1654-4811.4591/T+1.287lnp+1.046ln[C])·t/r02· The values calculated from the equation were consistent with the experimental results.

详情信息展示

Kinetics of iron removal from metallurgical grade silicon with pressure leaching

YU Zhanlianga, b, c, XIE Keqianga, MA Wenhuia, ZHOU Yanga, XIE Gangb, c, and DAI Yongniana a National Engineering Laboratory for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, China b Technology Center of Yunnan Metallurgy Group Co., Kunming 650031, China c Kunming Metallurgy Research Institute, Kunming 650031, China

摘 要:In this paper, the kinetics of pressure leaching for purification of metallurgical grade silicon with hydrochloric acid was investigated. The effects of particle size, temperature, total pressure, and concentration of hydrochloric acid on the kinetics and mechanism of iron removal were studied. It was found that the reaction kinetic model followed the shrinking core model, and the apparent activation energy of the leaching reaction was 46.908 kJ/mol. And the apparent reaction order of iron removal with pressure leaching was 0.899. The kinetic equation was ob-tained and the mathematical model of iron removal from metallurgical grade silicon (MG-Si) was given as follows: 1-2/3x-(1-x)2/3=exp(5.1654-4811.4591/T+1.287lnp+1.046ln[C])·t/r02· The values calculated from the equation were consistent with the experimental results.

关键词:

<上一页 1 下一页 >

有色金属在线官网  |   会议  |   在线投稿  |   购买纸书  |   科技图书馆

中南大学出版社 技术支持 版权声明   电话:0731-88830515 88830516   传真:0731-88710482   Email:administrator@cnnmol.com

互联网出版许可证:(署)网出证(京)字第342号   京ICP备17050991号-6      京公网安备11010802042557号