Ca、Zn双掺杂的SmAlO₃基氧离子导体的合成及电性能

来源期刊：中国有色金属学报2007年第6期

论文作者：向军 胥青华 王晓晖

文章页码：958 - 958

关键词：氧离子导电性；双掺杂铝酸钐；交流阻抗谱；电导率；

Key words：oxygen ionic conduction; doubly doped SmAlO₃; alternating current impendence spectrum; conductivity

摘    要：采用固相反应法合成一系列样品Sm_0.9Ca_0.1Al_1-xZn_xO_3-δ(x=0，0.03，0.05)。利用X射线衍射和扫描电镜研究样品的结构、微观形貌和烧结性能，用交流阻抗谱测量Sm_0.9Ca_0.1Al_0.97Zn_0.03O_3-δ在500~1 000 ℃的电导性能。结果表明：在1 650 ℃烧结24 h可以获得单相样品，Zn²⁺在B位的固溶度为3%~5%，样品的相对密度为92.3%。Ca、Zn双掺杂能大大提高样品的电导性能，800 ℃时总电导率为0.39 S/m，ln(sT)与1/T关系曲线呈一折线，高温电导活化能小于低温电导活化能，710 ℃以上的电导活化能为0.66 eV，710 ℃以下的电导活化能为1.18 eV。

Abstract: A series of samples Sm_0.9Ca_0.1Al_1-xZn_xO_3-δ(x=0, 0.03, 0.05) were synthesized by solid state reaction method. The microstructure, morphology and sinterability of the samples were characterized by X-ray diffraction and scanning electron microscope. And the alternating current impedance measurements were performed at 500~1 000 ℃. The results show that the single phase samples can be obtained when the samples are sintered at 1 650 ℃ for 24 h, and the solid solubility of Zn²⁺ on B site should be in the range of 3%~5%, and the relative density of Sm_0.9Ca_0.1Al_0.97Zn_0.03O_3？δ is 92.3%. The doubly doping of Ca and Zn can improve consumedly the electrical properties of SmAlO₃, and the total conductivity of Sm_0.9Ca_0.1Al_0.97Zn_0.03O_3-δ is 0.39 S/m at 800 ℃. The curves of ln(σT) against 1/T reveal two straight lines intersecting at 710 ℃. The activation energy of oxygen-vacancy motion above 710 ℃ is lower than that below 710 ℃