Upconversion emission of SrYbF5 :Er3+ nanosheets modified by Tm3+ ions
来源期刊:JOURNAL OF RARE EARTHS2013年第11期
论文作者:刘晴 颜晓红 陈远 王祥夫
文章页码:1053 - 1058
摘 要:Through a hydrothermal route,the Er3+and Tm3+co-doped SrYbF5nanosheets were synthesized.The resulting samples were characterized by X-ray diffraction,scanning electron microscopy,energy dispersive X-ray spectroscopy and luminescence spectra.Under the excitation of 980 nm laser irradiation,the upconversion emissions of Tm3+ions centered at 474 nm(1G4→3H6),679 nm(3F2→3H6),699 nm(3F3→3H6),803 nm(3H4→3H6)and emissions of Er3+ions centered at 522 nm(2H11/2→4I15/2),543 nm(4S3/2→4I15/2),654 nm(4F9/2→4I15/2)were observed.The upconversion emissions of Er3+ions were adjusted by the concentration of Tm3+ions.The energy transfer mechanisms among Er3+-Yb3+-Tm3+in SrYbF5nanosheets were discussed.
刘晴1,颜晓红1,2,陈远1,王祥夫2
1. College of Science, Nanjing University of Aeronautics and Astronautics2. School of Electronic Science and Engineering, Nanjing University of Posts and Telecommunications
摘 要:Through a hydrothermal route,the Er3+and Tm3+co-doped SrYbF5nanosheets were synthesized.The resulting samples were characterized by X-ray diffraction,scanning electron microscopy,energy dispersive X-ray spectroscopy and luminescence spectra.Under the excitation of 980 nm laser irradiation,the upconversion emissions of Tm3+ions centered at 474 nm(1G4→3H6),679 nm(3F2→3H6),699 nm(3F3→3H6),803 nm(3H4→3H6)and emissions of Er3+ions centered at 522 nm(2H11/2→4I15/2),543 nm(4S3/2→4I15/2),654 nm(4F9/2→4I15/2)were observed.The upconversion emissions of Er3+ions were adjusted by the concentration of Tm3+ions.The energy transfer mechanisms among Er3+-Yb3+-Tm3+in SrYbF5nanosheets were discussed.
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